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Q.

 The auxiliary reagent in group-IV reagent is:

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a

NH4OH

b

H2S

c

dil. HCl

d

NaOH

answer is D.

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Detailed Solution

Ammonium hydroxide is the auxiliary reagent found in group(iv).

Chemical auxiliaries are chemicals employed during a chemical synthesis but are not reagents since they are not integrated into the chemical product, such as solvents, separation agents, or dispersion agents.

Due to their low solubility products, group 3 cations are the only ions that precipitate as hydroxide when NH4OH is added. This is because group 3 cations have a lower solubility product than NH4OH.

Hence, the option D is correct.

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