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Q.

The average Xe-Fbond energy is 34 kcal/mol. First I.E.. of Xe is 279 kcal/mol, electron affinity of F is 85 kcal/mol and bond dissociation energy of F2 is 38 kcal/mol. Then the enthalpy change for the reaction 

XeF4Xe++F+F2+F will be:

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a

367 kcal/mole 

b

 425 kcal/mole 

c

 292 kcal/mole

d

 392 kcal/mole 

answer is C.

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Detailed Solution

The given Value

XeF4Xe+4F ΔH=34×4=136

XeXe+e ΔH=279

F+eF ΔH=85

F22F ΔH=38

Totally the equation 

XeF4Xe++F+F2+F

ΔH=136+2798538 =292

the enthalpy change for the reaction 

XeF4Xe++F+F2+F will be:  292 kcal/mole

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