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Q.

The basicity of acids obtained from the hydrolysis of NCl3 and PCl3 respectively

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a

0 and 2 , 1

b

1 and 2 , 1

c

2 and 1, 1

d

1 and 2 , 2

answer is B.

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Detailed Solution

Hydrolysis of NCl3 and PCl3 are:

NCl3  + 3H2O   NH3 + 3HOCl   PCl3 + 3H2O  3HCl + H3PO3 

Basicity of an acid is calculated by the number of hydrogen ions which can be released by an acid in an aqueous solution. 

  • Basicity of HOCl is 1 as it has one hydrogen ion
  • H3PO3 has basicity 2 because it has two ionisable hydrogen ions
  • HCl has basicity one as it has one ionisable ion in the aqueous solution.
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