Q.

The best method for the conversion of an alcohol into an alkyl chloride is by treating the alcohol with

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a

PCl5

b

SOCl2  in presence of pyridine

c

PCl3

d

Dry   in the presence of anhydrous  ZnCl2

answer is B.

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Detailed Solution

 ROH+SOCl2refluxpyridineRCl+SO2+HCl . The Bye-products  SO2,HCl gases and no need to separate.

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The best method for the conversion of an alcohol into an alkyl chloride is by treating the alcohol with