Q.

The binary liquid mixture which shows positive deviations from Raoult's law is

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a

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b

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c

CS2+CH3COCH3

d

CHCl3+CH3COCH3

answer is A.

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Detailed Solution

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Acetone-Acetone….diople-dipole attractions;

Carbon disulphide-Carbon disulphide….dispersion forces;

Dipole-Dipole attractions in acetone are disturbed by the addition of carbon disulphide;

A-B interactions are weaker than in A-A and B-B;

The mixture shows positive deviations from Raoult's law;

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