Q.

The black precipitate of nickel sulphide dissolves in aqua regia  and the reaction takes place as follows:
3NiS+2HNO3+6HCl 3NiCl2+2NO+3S+4H2O
After treatment with aqua regia nickel-chloride is obtained which is soluble in water. when dimethyl glyoxime is added to the aqueous solution of nickel chloride, made alkaline, by adding NH4OH  solution, a brilliant red precipitate is obtained. Find sum of the number of  NiN linkages and  NiClinkages in brilliant red precipitate. 

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answer is 4.

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Detailed Solution

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[Ni(dmg)2]0

Have four NiN linkage

Have zero NiC linkage 

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