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Q.

The boiling point of 0.2 mol kg- solution of X in water is greater than equimolal solution of Y in water. Which one of 
the following statements is true in this case ?  

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a

Molecular mass of X is greater than the molecular mass of Y. 

b

Molecular mass of X is less than the molecular mass of  Y

c

Y is undergoing dissociation in water while X  undergoes no change. 

d

X is undergoing dissociation in water.  

answer is D.

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Detailed Solution

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Expression of elevation in boiling point:

ΔTb=iKbm
Given that:

ΔTbX>ΔTbY

Kb is the constant and it is same because solvent is the same. Value of m is also same. Hence, the only change in Tb value is due to the value of i (Van't Hoff factor).

iX>iY

This indicates that X undergoes dissociation in water.

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