Q.

The boiling point of 0.2 mol kg-1 solution of X in water is greater than equimolal solution of Y in water. Which one of the following statements is true in this case?

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a

X is undergoing dissociation in water

b

Molecular mass of X is less than the molecular mass of Y

c

Molecular mass of X is greater than the molecular mass of Y

d

Y is undergoing dissociation in water while X undergoes no change

answer is D.

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Detailed Solution

ΔTbx>ΔTby
As same solvent is used so, Kb is same for both X and Y As m is same (given) so ix.kb.m > iy. kb. m
ix > iy. Hence x is undergoing dissociation in water.

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