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Q.

The boiling point of diethyl ether is ${34.6}^{\circ} C .$ Which is true for the vaporization of diethyl ether at 25.0° C?

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a

$K_{vap} = 1$

b

$Δ S_{vap}^{\circ} < 0$

c

$Δ G_{vap}^{\circ} > 0$

d

$Δ H_{vap}^{\circ} < 0$

answer is A.

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Detailed Solution

At a temperature below B.P., vaporisation is non-spontaneous.

For nonspontenuse process we know that,

$Δ G_{vap}^{\circ} > 0$

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The boiling point of diethyl ether is 34.6∘C. Which is true for the vaporization of diethyl ether at 25.0° C?