Q.

The boiling point of water (100° C) becomes 100.52°C, if 3 grams of a nonvolatile solute is dissolved in 200ml of water. The molecular weight of solute is (Kb forwateris 0.6K-kg mol-1 ) 

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a

20.4 g mol

b

12.2 g mol-1

c

17.3 g mol-1

d

15.4 g mol

answer is C.

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Detailed Solution

First boiling point of water = 100°C,

 Final boiling point of water = 100.52°

w(solute)=3g,W(solvent)=200g,Kb=0.6Kkgmol1ΔTb=100.52100=0.52C

m=Kb×w×1000ΔTb×W=0.6×3×10000.52×200=1800104=17.3gmol1.

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