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Q.

The bond angle in H2O is approximately 105while the bond angle in H2S is approximately 90. Which explanation best accounts for this difference?

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a

HS bonds are longer than HS bonds,

 

b

S has d orbitals available for bonding, O does not

c

HS  bonds are less polar than HO bonds.

d

O uses sp3 hybrid orbitals for bonding, S uses its 3p orbitals.

answer is D.

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Detailed Solution

According to Drago's rule, in the following circumstances, it is not necessary  to pay attention to an element's hybridization: Case 1: The centre atom of the molecule has at least one lone pair of electrons. Case 2: The centre atom can be made up of any of the elements from groups 13, 14, 15, or 16 or from the third to seventh period.

Hence, the correct answer is D.

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