Q.

The bond dissociation energy is highest for

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a

CI2

b

I2

c

F2

d

Br2

answer is C.

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Detailed Solution

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C2>Br2>F2>I2Bond dissociation energy of halogen family decreases down the group as the size of atom increases. The decreasing order for the bond dissociation enthalpy of halogen molecules is Cl2​ 57 kcal/mol>Br2​ 45.5 kcal/mol>F2​ 38 kcal/mol> I235.6 kcal/mol. A halogen molecule having larger atoms should have low dissociation energy and vice versa. Fluorine is an exception because of interelectronic repulsion is present in small atom fluorine.

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