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Q.

The bond enthalpies of CC,C=C and C  C bonds are 348,610 and 835 kJ/mole respectively at 298 K and 1 bar. Calculate enthalpy of polymerisation per mole of 2 butyne at 298 K and 1 bar :

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a

-123 kJ 

b

- 37 kJ 

c

- 139 kJ 

d

-132 kJ 

answer is A.

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Detailed Solution

Change in the enthalpy for the following reaction can be calculated as

CH3CCCH3Question Image

ΔHreaction =835610348=123kJ

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