Q.

The bond length in CO is 1.128 A. What will be the bond length of CO in Fe(CO)5?

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a

1.158 A

b

1.128 A

c

1.108 A

d

1.118 A

answer is A.

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Detailed Solution

Synergic bonding is generally observed in coordination compounds, where there is transfer of electrons from filled orbitals of metals to anti-binding of ligands. This strengthens the bond between metal and ligand. In Fe(CO)5, there is synergic bonding between Fe and CO, this increases the bond length between C=O, thereby bond order of C=O decreases. Among given options, only 1.158 A is greater than the given bond length value of CO, 1.128 A.

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