Q.

The bond length of HCl molecule is 1.275 Ao and its dipole moment is 1.03 D. The ionic character of the molecule (in per cent) ( charge of the electron=4.8×10-10  esu) is

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a

100

b

67.3

c

33.66

d

16.83

answer is D.

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Detailed Solution

Given,
observed dipole moment = 1.03 D
Bond length of HCl molecule, d = 1.275 Ao   = 1.275 ×10-8  cm 
Charge of electron, e-=4.8×10-10  esu
Percentage ionic character = ?
Theoretical value of dipole moment = e×d
                           =4.8×10-10×1.275×10-8  esu.cm
                           =6.12×10-18  esu.cm   = 6.12 D
Percentage ionic character

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