Q.

The bond order and magnetic characteristics of CN- are :

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a

212, paramagnetic 

b

3, paramagnetic 

c

 3, diamagnetic 

d

212, diamagnetic 

answer is A.

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Detailed Solution

CN-is a 14 electron system. The bond order and magnetism can be predicted using MOT. The MOT electronic configuration of CN-is:
σ1 s2σ1 s*2σ2 s2σ2 s*2π2px2=π2py2σ2pz2

Bond order =1/2Nbonding -Nantibonding =3
As CN-does not have any unpaired electrons, and hence it is diamagnetic.

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The bond order and magnetic characteristics of CN- are :