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Q.

The bond order of O2+ is x. The bond order of O2 and O22+ are respectively.

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a

25X,35X

b

53X,56X

c

52X,53X

d

35X,65X

answer is B.

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Detailed Solution

Bond order (BO)
12Number  of   bonding         eNumber  ofantibonding   e
Electronic configuration
O2+=σls2σls2,σ2s2,σ2s2,σ2pz2        π2px2=π2py2,π2px1=π2py0
BO=12[105]=52
BO  of  O2+=x(given)  52=x         ....(1)
O2=σls2,σls2,σ2s2,σ2s2,σ2pz2        π2px2=π2py2,π*2px2π*2py1
BO=12[107]=32OrBO  of  O2=3x5     ....[From (1)]
O22+=σls2,σls2,σ2s2,σ2s2,σ2pz2        π2px2=π*2py1
BO=12[104]=62OR6x5[From(1)]

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The bond order of O2+ is x. The bond order of O2− and O22+ are respectively.