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Q.

The Born-Haber cycle for KCl is evaluated with the following data:
ΔfH0   for  KCl  =436.7   KJmol1;
ΔsubH0   for  K  =89.5    KJmol1;
Δionization  H0   for  K=419.0  KJmol1;
Δelectron   gain   enthalpyH0   for  Clg=348.6  KJmol1;
Δbond  dissiociation  energyH0   for  Cl2=243.0   KJmol1;
The magnitude of lattice enthalpy of KCl in KJmol-1  is ___ (Nearest integer)

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a

718

b

840

c

597

d

763

answer is C.

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Detailed Solution

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U=ΔHf+SE+IE+12BEEA
=436.789.5+419.0+12243.0348.6=718.1

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