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Q.

The (C – H) bond length order in hydro-carbons in which the hybridisation of carbon is sp3 or sp2 or sp

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a

sp – s > sp2 – s > sp3 – s

b

sp – s = sp2 – s = sp3 – s

c

sp3 – s > sp2 – s > sp – s

d

sp3 – s > sp – s > sp2 – s

answer is C.

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Detailed Solution

Bond Order is directly proportional to Bond Strength and inversely proportional to Bond Length (stronger is the bond, more is the B.O. and smaller is the B.L.)

In sp3 – s bond, B.O. = 1 (C-C)

In sp2 – s bond, B.O. = 2 (C=C)

In sp – s bond, B.O. =  3 (CC)

Thus, B.L. = sp3 – s > sp2 – s > sp – s.

Hence, the correct option is option (C) sp3 – s > sp2 – s > sp – s.

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