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The carbocation with least stability is

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${CH}_{3} - {CH}_{2} - \overset{+}{C} H_{2}$

$O_{2} N - {CH}_{2} - \overset{+}{C} H_{2}$

$Cl - {CH}_{2} - \overset{+}{C} H_{2}$

$F - {CH}_{2} - \overset{+}{C} H_{2}$

answer is B.

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Detailed Solution

-I effect

$- {NO}_{2} > - F > - Cl$
$- {CH}_{2} - {CH}_{3} group shows + I effect .$
+I groups stabilize carbocation by dispersing the positive charge.
-I groups destabilize carbocation by intensifying the positive charge.

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