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Q.

The carbon atoms involved in osazone formation are : ____

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a

5 and 6

b

3 and 4

c

2 and 3

d

1 and 2

answer is B.

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Detailed Solution

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Reaction sequence:

Glucose+C6H5NHNH2    H2O    CH=NNHC6H5Glucose + C_6H_5NHNH_2 \;\;\xrightarrow{-H_2O}\;\; CH=NNHC_6H_5

                CHOH      (CHOH)3      CH2OH\;\;\;\;\; | \\ \;\;\; CHOH \\ \;\;\; (CHOH)_3 \\ \;\;\; CH_2OH     C6H5NH2,NH3C6H5NHNH2\;\;\xrightarrow[{ -C_6H_5NH_2, NH_3 }]{ C_6H_5NHNH_2 } 

 

CH=NNHC6H5      C=O(CHOH)3CH2OH    C6H5NHNH2CH=NNHC_6H_5 \;\;\; | \\ C=O \\ (CHOH)_3 \\ CH_2OH \;\;\xrightarrow{ C_6H_5NHNH_2 }

CH=NNHC6H5      C=NNHC6H5+H2O(CHOH)3CH2OHCH=NNHC_6H_5 \;\;\; | \\ C=NNHC_6H_5 + H_2O \\ (CHOH)_3 \\ CH_2OH

Product: Osazone

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