Q.

The cell potential for the following cell  Pt|H2(g)|H+(aq)Cu2+(0.01M)Cu(s) is 0.576 V at 298 K. The pH of the solution is ___. (Nearest integer)

 

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answer is 5.

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Detailed Solution

by using nernst equation Anode:H22H++2e Cathode : Cu2++2eCu Cu2++H22H++Cu Ecell =Ecell 00.062logH+2Cu2+ 0.576=0.340.062logH+2(0.01) +3.93log(H+)+log0.1pH=4.935

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