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Q.

The cell potential of the cell PtH2g, 0.25 atm|HCl(aq, c)|H2(g, 0.5 atm)Pt at 25 °C  is.

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a

+0.0177V

b

+0.00885V

c

0.0177V

d

0.00885V

answer is C.

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Detailed Solution

The cell reaction is 

Reduction at right-hand electrode 2H+(aq)+2eH2(g)R

Oxidation at left-hand electrode  H2(g)L2H+(aq)+2eH2(g)LH2(g)R

The cell potential is

Ecell =RT2FlnpH2RpH2L=0.059V2log0.50.25=0.059V2(0.30)=0.0089V

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