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Q.

The CFSE for octahedral [CoCl6 ] 4– is 18,000 cm–1. The CFSE for tetrahedral [CoCl4 ] 2– will be 

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answer is 8000.

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Detailed Solution

[CoCl6​]4− and [CoCl4​]2− have octahedral and tetrahedral geometries respectively.

For [(CoCl6​]4−, the CFSE Δo​=18000cm−1.

The relationship between the crystal field stabilization energies for octahedral and tetrahedral field is t =49 0

Substitute value in the above expression to determine the value of CFSE in [CoCl4​]2−

t =49×18000 cm1- t =8000 cm1-

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