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Q.

The CFSE for octahedral ${({CoCl}_{6})}^{4 -}$ complex is $18000 {cm}^{- 1}$ . Then CFSE for tetrahedral ${({CoCl}_{4})}^{2 -}$ will be

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a

$16000 {cm}^{- 1}$

b

$8000 {cm}^{- 1}$

c

$2000 {cm}^{- 1}$

d

$18000 {cm}^{- 1}$

answer is B.

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Detailed Solution

$Δ t = \frac{4}{9} Δ 0 \Rightarrow \frac{4}{9} \times 18000 = 8000 {cm}^{- 1}$

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