Q.

The CFSE value of an octahedral complex is −0.6 o. If metal ion is surrounded by weak ligands, the magnetic moment can be (spin only)

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a

5.91 BM

b

3.8 BM

c

4.9 BM

d

Zero

answer is A.

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Detailed Solution

Given CFSE value obtained when there are four unpaired electrons ( 3 in t2g and 1 in eg).

CFSE=-0.4n+0.6n=-0.4×3+0.6×1=-0.6

magnetic moment μ:

μ=n(n+2)=4(4+2)=4.9 BM

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