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Q.

The change of optical rotation of glucose solution with time is refered to as:

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a

inversion

b

mutarotation

c

specific rotation

d

autorotation

answer is A.

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Detailed Solution

Mutarotation is the change in the optical rotation with time that occurs by epimerization (that is the change in the equilibrium between two epimers, when the corresponding stereocenters interconvert). Cyclic sugars show mutarotation as α and β anomeric forms interconvert.  

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