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Q.

The color exhibited by one of the iron ions in aqueous solutions is pale green. The primary valency and secondary valency respectively in the green complex are

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a

2, 6

b

2, 4

c

3, 6

d

3, 4

answer is A.

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Detailed Solution

As per the question, the presence of a pale component can be attributed to [Fe(H2O)4]2+, thus primary valency can be calculated as x where : x + (4×0) = 2, x = 2. 
The number of ligands would denote the secondary valency, therefore 4.

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