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Q.

The colour of the X2 molecules of group 17 elements changes gradually from yellow to violet down the group. This is due to

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a

The physical state of X2 at room temperature changes from gas to solid down the group 

b

Decrease in HOMO-LUMO gap down the group

c

Decrease in π*O* gap down the group

d

Decrease ionization energy down the group

answer is B, C.

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Detailed Solution

IF Consider, X2 as F2

F2MoT config is σ/s2σ/s2σ2s2σ2s2σ2pz2π2px2=π2py2π2px2=π2py2 HOMO σ2pz0LuMo

Þ if gap between HOMO & LUMO Due to absorbed energy decreases

Þ complimentary colour is seen

Þ light energy is seen

Þ both ‘B’ & ‘C’ are thus applicable

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