Q.

The combustion of one mole of liquid benzene takes place at 290K and 1 atm. After combustion,  CO2(g) and  H2O(l) are produced and 3267.0 Kj of heat produced. Standard enthalpy of formation of  CO2(g) and  H2O(l) are -393.5 kj/mol and -285.8 kj/mol respectively. The standard enthalpy of formation of liquid benzene in kj/mol is

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answer is 48.6.

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Detailed Solution

NCERT P.No: 170

C6H6(l)+152O2(g) 6CO2(g)+3H2O(l)            3267=(6×393.5+3×285.8)(ΔfH0C6H6(l)+7.5×0)            ΔH0fC6H6(l)=+48.6kg/mol

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