Q.

The complex(es), which can exhibit the type of isomerism shown by [Pt(NH3)2Br2], is(are) [en = H2NCH2CH2NH2]

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a

[Zn(NH3)2Cl2]

b

[Cr(en)2(H2O)(SO4)]+

c

[Pt(en)(SCN)2]

d

[Pt(NH3)2Cl4]

answer is C, D.

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Detailed Solution

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PtNH32Br2-SquarePlanar                          -Geometricalisomerism 
ZnNH32Cl2 -tetrahedralcomplex                            -does not exhibit G.I 
M(aa)b2 Square planar                  -does not exhibit G.I 
Cren2H2OSO4+:Maa2bcOctahedralexhibitG.I

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