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Q.

The complex (ex), which can exhibit the type of isomerism shown by [Pt(NH3)2Br2],   is (are) [en=H2NCH2CH2NH2] 

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a

[Cr(en)2H2O)(SO4)]+

b

[Zn(NH3)2Cl2]

c

[Pt(en)(SCN)2]

d

[Pt(NH3)2Cl4]

answer is C, D.

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Detailed Solution

The given complex [Pt(NH2)2Br2] is a square planar complex and shows geometrical isomerism, i.e. (cis and trans)
(A) [Pt(en)(SCN)2]  Cannot show geometrical isomerism. 
(B) [Zn(NH3)2Cl2] is a tetrahedral complex and hence, cannot show geometrical isomerism. 
(C)  [Pt(NH3)2Cl4] is a octahedral complex and hence, shows geometrical isomerism. 
(D) [Cr(en)2(H2O)(SO4)]+ Is an octahedral complex and is of one type. [M(AA)2bc]  can show  
 Geometrical isomerism.
Where M=Cr,(AA)=(en),b=H2Oandc=SO4  
 

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