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Q.

The complex having highest  value

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a

[Ni(en)3]2+

b

[Ni(CN)4]2-

c

[NiCl4]2-

d

[Ni(NH3)6]2+

answer is B.

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Detailed Solution

sp >  > f  ;  sp  1.3 

Therefores CFSE value of [Ni(CN)4]2- is greater than [Ni(en)3]++ or [Ni(NH3)6]++ or [NiCl4]2- Also CN- is very strong liquid.

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