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Q.

The complex in CoCO333 has one absorption band in the visible region of the spectrum at 640 nm. From this information 

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a

The complex is blue in colour.

b

The complex is paramagnetic with magnetic moment 4.9 BM

c

Carbonate ion is weak ligand, so o is small and hence it should be high spin complex

d

It can exhibit both optical and geometrical isomerism

answer is A, C, D.

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Detailed Solution

The light absorbed is in the orange region (640 nm) of the spectrum therefore, the light transmitted (the colour of the solution) is blue. From the wave length of light absorbed confirms that 0 is small. So CO32 is weak ligand. Hence the complex is high spin and paramagnetic with 4 unpaired electrons.

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