Q.

The complex ions Fe(CN)63 and Fe(CN)64 :

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a

Have different structure but opposite magnetic character

b

 Are both octahedral and diamagnetic

c

Are both octahedral and paramagnetic

d

Have same structure but opposite magnetic character

answer is C.

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Detailed Solution

Since Fe(CN)64 and Fe(CN)63has zero or one unpaired electrons. As a result, they both differ in their magnetic property.
Electronic configuration of Fe(CN)64  is 4s23d6( diamagnetic).
Electronic configuration of Fe(CN)63  is 4s23d5 (paramagnetic).

Thus, the correct option is c.

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