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Q.

The complexes [Co(NH3)5NO2 ]Cl2 and  [Co(NH3)5(ONO)]Cl2  are the examples of

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a

optical isomers

b

geometrical isomers

c

linkage isomers

d

coordination isomers

answer is D.

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Detailed Solution

The complexes [Co(NH3)5NO2 ]Cl2 and  [Co(NH3)5(ONO)]Cl2  are the examples of linkage isomers.

Two or more coordination compounds called linkage isomers have at least one ligand with a different donor atom than the others (i.e., the connectivity between atoms is different). Only a ligand that can form two (or more) distinct bonds with the metal atom may cause this kind of isomerism in a molecule.

Hence, option D is correct.

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