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Q.

The compound having shortest $S - O$ bond length is

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a

${SOCl}_{2}$

b

${SO}_{3} F^{-}$

c

$S {O_{4}}^{2 -}$

d

${SOF}_{4}$

answer is A.

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Detailed Solution

Bond length is basically the average distance between nucleus of 2 bonded atoms in a molecule.
The compound having shortest S−O bond length is ${SO}_{3} F^{-}$ , as sulfur has 6 valence electrons and 5 of them are in bonding with oxygen and fluorine is a strongly EN atom.
So, it attracts the electrons towards it strongly and reduces the bond length.

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