The compound obtained by addition of water to an alkyne having more than two carbons, in presence of HgSO₄ at 333 K, is

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an alcohol

an aldehyde

a ketone

a vicinal diol

answer is C.

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Detailed Solution

Hydration of ethyne gives aldehyde but hydration of alkynes having more than 2 carbons gives ketone. Lets assume, propyne as our alkyne.
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