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Q.

The compound obtained by heating a mixture of a primary amine and chloroform with ethanolic potassium hydroxide KOH is

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a

an alkyl cyanide

b

a nitro compound

c

an alkyl isocyanide

d

an amide

answer is C.

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Detailed Solution

We know that CH3CH2NH2+CHCl3+3KOHCH3CH2NC+3KCl+3H2O
In this reaction, bad smelling compound ethyl isocyanide CH3CH2NC is produced. This equation is known as carbylamine reaction.

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The compound obtained by heating a mixture of a primary amine and chloroform with ethanolic potassium hydroxide KOH is