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Q.

The compound of vanadium has magnetic
moment of 1.73 BM. The vanadium chloride
has the formula:

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a

VCl4

b

VCl5

c

VCl2

d

VCl3

answer is C.

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Detailed Solution

We know that Electronic configuration of vanadium is 

V(23):1s22s22p63s23p63d34s2

Now, we also know that 

Magnetic moment =n(n+2)BM=n(n+2)=1.73BM (Given)

Thus, n=1 (one unpaired electron)

Now Electronic configuration of vanadium with one unpaired electron is 

V4+:1 s22 s22p63 s23p63 d1.

Therefore,its chloride is VCl4.

Hence, option(c) is the answer.

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The compound of vanadium has magneticmoment of 1.73 BM. The vanadium chloridehas the formula: