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Q.

The compound P, Q and S

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were separately subjected to nitration using HNO3/H2SO4 mixture. The major product formed in each case respectively is

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a

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b

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c

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d

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answer is C.

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Detailed Solution

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Product is w.r.t to –OH as this reaction is electrophilic substitution and OH group is activating.

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Product is w.r.t – OCH3 as it is more ring activating than CH3

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Benzene ring to which     O     || -C- is attached becomes deficient in electrons due to – R nature of group. Rather to which –O– is attached becomes e¯ rich due to lone pair so product will be on that ring.

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