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The compound that has the largest H-M-H bond angle M = N, O, S, C) is

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H₂S

CH₄

NH₃

H₂O

answer is D.

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Detailed Solution

[CH₄ = hybridisation is sp³ , lone pair of electrons is 0, so that bond angle is maximum, i.e. = 109°28'

NH₃ = Hybridisation is sp³, lone pair of electron is one, so that bond angle is 107°

H₂O = Hybridisation is sp³ lone pair of electrons are two, so that bond angle is 104°5'

No hybridisation as according to Draga's rule, so that bond angle is 92°

According to VSEPR theory.
Lone pair-Lone pair > Lone pair-Bond pair > Bond pair-Bond pair.

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