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The compressibility factor of gas is less than unity at STP, therefore

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$V_{m} (molar volume) > 22 .4 L$

$V_{m} < 22.4 L$

$V_{m} = 22 .4 L$

$V_{m} = 44 .8 L$

answer is B.

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Detailed Solution

$\frac{pV}{RT} = Z, Z < 1 ∴ \frac{pV}{RT} < 1 at STP \frac{p}{RT} = \frac{1}{0 .0821 \times 273} = \frac{1}{22 .4} \Rightarrow \frac{V_{m}}{22 .4} < 1 ∴ V_{m} < 22 .4 L$

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