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Q.

The concentrations of acetic acid and sodium acetate is a buffer solution of total moalrity 0.39 M and having a pH of 4.4 if the Ka of acetic acid is  is 1.83×10-5 is

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a

0.13; 0.26

b

0.18; 0.21

c

0.30; 0.09

d

0.26;  0.13

answer is A.

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Detailed Solution

Ka=10-4.2=6.31×10-5,log[Salt][Acid]=pH-pKa

=pH+logKa=4.4+log(1.83×10-5)= 4.4 – 4.7 = - 0.3 

[Salt][Acid]=10-0.3=0.5  1+[Salt][Acid]=1+0.5

[Acid]+[Salt][Acid]=1.5 , total  molarity[Acid]=1.50.39[Acid]=1.5

[Acid]=0.391.5=0.26  [Salt] = 0.39 – 0.26 = 0.13

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