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Q.

The condition of spontaneity of process is 

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a

Lowering of entropy at constant temperature an: pressure 

b

Lowering of Gibbs free energy of system at constant temperature and pressure 

c

Increase of entropy of system at constant temperature and pressure 

d

Increase of Gibbs free energy of the universe a: 
constant temperature and pressure 

answer is B.

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Detailed Solution

  • From Gibbs-Helmholtz equation ΔG = ΔH − TΔS
  • A process will be spontaneous, if ΔG = −ve.
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The condition of spontaneity of process is