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Q.

The conductance of a 0.0015 M aqueous solution of a weak monobasic acid was determined by using conductivity cell consisting of platinized 'pt' electrodes. The distance between the electrodes is 120 cm with an area of cross section of 1 cm2.The conductance of this solution was found to be 5 × 10-7S. The pHof the solution is 4.  The value of limiting molar conductivity omof this weak monobasic acid in aqueous solution is z × 102 S cm-1 mol-1.The value of zis ……

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answer is 6.

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Detailed Solution

K = G × lA

=5×10-7S cm-1×120 cm1 cm2

=6×10-5S cm-1

pH=4,  H+=10-4=c  α

α=1040.0015

α=mcmo

1040.0015=6×105×10000.0015×mo

om=6×102                 Z=6

mc=k × 1000C

=6×105×10000.0015

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The conductance of a 0.0015 M aqueous solution of a weak monobasic acid was determined by using conductivity cell consisting of platinized 'pt' electrodes. The distance between the electrodes is 120 cm with an area of cross section of 1 cm2.The conductance of this solution was found to be 5 × 10-7S. The pHof the solution is 4.  The value of limiting molar conductivity ∧omof this weak monobasic acid in aqueous solution is z × 102 S cm-1 mol-1.The value of zis ……