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Q.

The conductivity of 0.001 M acetic acid is 5 × 10–5 S cm–1 and Λo is 390.5 S cm2 mol–1 then the calculated value of dissociation constant of acetic acid would be ____ × 10–6

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answer is 18.78.

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Detailed Solution

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ΛM=(K×1000)/M;α=ΛM/ΛM0Ka=2

λM=5×10-5×10000.001=50

α=50390.5=0.128

Ka=α2C=(0.128)2×0.001=16×10-6

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