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Q.

The conductivity of saturated solution of AgCl is found to 1.86×106ohm1cm1 and that of water is 6×108ohm1cm1. If λ0AgCl is 138 ohm1cm2eq1 the solubility product of AgCl is 

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a

1.69 × 10–10

b

2 × 10–10

c

1.3 × 10–5

d

2.7 × 10–10

answer is B.

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Detailed Solution

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Conductivity of AgCl = Conductivity of solution - Conductivity of water 

= 1.8 × 10-6 ohm-1cm-1

λM0=κ×1000M

M=1.8×10-6×1000138=0.013 ×10-3=1.3×10-5

Ksp =1.3×10-52=1.69×10-10

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