Q.

The coordination number and the oxidation state of the element E in the complex E(en)2C2O4NO2, where en is ethylenediamine, are respectively

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a

6 and 2

b

6 and 3

c

4 and 2

d

4 and 3

answer is A.

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Detailed Solution

Both en and C2O42 are bidentate ligands. Hence, the coordination number ofE is 2 x 2 + 2 = 6. Its oxidation state is +III since C2O42 and NO2 carry a total of three negative charge.

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The coordination number and the oxidation state of the element E in the complex E(en)2C2O4NO2, where en is ethylenediamine, are respectively