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Q.

The correct acidity order of the following is

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a

IV > III > I > II

b

III > II > I > IV

c

I > II > IV > III

d

II > I > IV > III

answer is D.

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Detailed Solution

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Electron withdrawing groups increase the acidity of carboxylic acids by stabilising the
conjugate base through delocalisation of the negative charge by inductive and/or resonance effects. Conversely, electron donating groups decrease the acidity by destabilising the conjugate base.

The effect of the following groups in increasing acidity order is
Ph < I < Br < Cl < F < CN < NO2 < CF3

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